When chromite ore (A) is fused with sodium carbonate in excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. On treating B with sulphuric acid, compound (C) can be crystallized from the solution. When compound (C) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A and D. 

1
PbCrO4, K2CrO4
2
PbCrO4, K2Cr2O7
3
FeCr2O4, K2CrO4
4
FeCr2O4, K2Cr2O7

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