Which of the following reactions of methane is incomplete combustion:

1
2CH4 + O2 \(\rm \xrightarrow{Cu/523\ K/100atm}\) 2CH3OH
2
CH4 + O\(\rm \xrightarrow{Mo_2O_3}\) HCHO + H2O
3
CH4 + O2 → C(s) + 2H2O (l)
4
CH4 + 2O2 → CO2 (g) + 2H2O (l)

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