Which molecular interaction is described by the term "σ-hole interactions" in the context of supramolecular chemistry?

1
Interaction between cations and anions through electrostatic forces
2
 Interaction between a metal cation and an electron-rich donor atom via a positively polarized region
3
Interaction between two π-electron systems in aromatic molecules
4
Interaction between a polar molecule and a hydrophobic molecule

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