Thermal decomposition of a Mn compound (X) at 513 K results in compound Y, MnO2 and gaseous product MnO2 reacts with NaCl and concentrated H2SO4 to give a pungent gas Z, X, Y and Z, respectively, are:

1
K3MnO4, K2MnO4 and Cl2
2
K2MnO4, KMnO4 and SO2
3
KMnO4, K2MnO4 and Cl2
4
K2MnO4, KMnO4 and Cl2

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