In the electrochemical cell:

Zn | ZnSO4 (0.01 M) || CuSo4(1.0 M)Cu the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that of CuSO4 Changed to 0.01M, the emf changes to E2. From the followings which one is the relationship between E1 and E2?

(Given RT/F = 0.059) 

1
E1 = E2
2
E1 < E2
3
E1 > E2
4
E2 = 0 ≠ E1

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