The experimental magnetic moment (3.4 BM) of a hydrated salt of Eu3+ at 27° C is significantly different from the calculated value. The difference is due to

(Given: atomic number of Eu is 63)

1
Population of electrons at higher J level(s) via thermal excitation.
2
strong ligand field splitting of f-orbitals.
3
strong spin-orbit coupling.
4
pairing of electrons in f-orbitals
5
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