The major product formed in the reaction of D-glucose with ZnClin MeOH is a methyl glucopyranoside (A or B). The structure of this product and the molecular orbital interaction present between ring-oxygen and the anomeric C-O bond responsible for its stability, respectively, are

1
A and n → σ*
2
A and n → σ
3
B and n → σ*
4
B and n → σ
5
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