Arrange the following water quality parameters in ascending order of their typical concentration in natural freshwater systems:

1. Nitrates

2. Phosphates

3. Total Dissolved Solids (TDS)

4. Heavy metals (e.g., lead, mercury)

1
4, 1, 2, 3
2
2, 4, 1, 3
3
3, 2, 1, 4
4
1, 2, 3, 4

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