If \(M and R\) are specific gas and air constant respectively, identify the correct expression of Vapour Pressure Deficit (VPD). 

1
\({VPD} = \frac{M}{R} \cdot \frac{dT}{dt}\)
2
\({VPD} = \frac{M}{R} \cdot \frac{T}{T_s} \)
3
\({VPD} = \frac{M}{R} \cdot \left(1 - \frac{RH}{100}\right) \)
4
\({VPD} = \frac{M}{R} \cdot \frac{e}{e_s}\)

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