Secondary pollutants are formed in the atmosphere by which of the following reactions?

1
A reductive reaction that include ozone (03) and peroxyacetyl nitrate (PAN)
2
A hydrolytic reaction that includes hydrocarbons and oxygen
3
A photochemical reaction, hydrolysis or oxidation and include ozone (O3) and peroxyacetyl nitrate (PAN)
4
An oxidative reaction that includes methane and ozone

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