Comprehension Passage

Read the following passage and answer questions
Greater is the stability of the substituted ammonium cation, stronger should be the corresponding amine as a base. Thus, the order of basicity of aliphatic amines should be :
primary > secondary > tertiary, which is opposite to the inductive effect based order.

Secondly, when the alkyl group is small, like -CH3 group, there is no steric hinderance to H- bonding. In case the alkyl group is bigger than -CH3 group, there will be steric hinderance to H-bonding. Therefore, the change of nature of the alkyl group, e.g., from -CH3 to -C2H5 results in change of the order of basic strength. Thus, there is a subtle interplay of the inductive effect, solvation effect and steric hinderance of the alkyl group which decides the basic strength of alkyl amines in the aqueous medium.

Which base among the following is least basic in aqueous medium?

1
(CH3)2NH
2
CH3NH2
3
(CH3)3N
4
NH3

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