For the following reaction : 

N2(g) + 3H2(g) ⇋ 2NH3(g)

The free energy changes at 25°C and 35°C are -33.089 and -28.018 kJ respectively. The heat of the reaction is 

1
+184.20 kJ
2
-184.20 kJ
3
-33.089 kJ
4
+33.089 kJ

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