Identify the wrong relation for real gases :
1
\(Z=\frac{V_{\text {ideal }}}{V_{\text {real }}}\)
2
\(\mathrm{p}_{\text {ideal }}=\mathrm{p}_{\text {real }}+\frac{\mathrm{an}^2}{\mathrm{~V}^2}\)
3
\(\mathrm{V}_{\text {real }}=\mathrm{V}_{\text {ideal }}-\mathrm{nb}\)
4
\(\left(\mathrm{p}+\frac{\mathrm{a}}{\mathrm{~V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}\)