AgNO3 solution does not give white ppt. with CCl4 but with sodium extract of CCl4, AgNO3 gives white precipitate because:

1
CCl4 is covalent compound
2
CCl4 is partially ionised
3
Sodium extract of CCl4 contains Cl ions and Na+ ion
4
Sodium extract of CCl4 contains ClO3 ions

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