The orange colour of K2Cr2O7 and purple colour of KMnO4 is due to

1
Charge transfer transition in both.
2
d→d transition in KMnO4 and charge transfer transitions in K2Cr2O7.
3
dd transition in K2Cr2O7 and charge transfer transitions in KMnO4.
4
d→d transition in both.
5
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