A large sudden jump between the values of second and third ionization energies of an atom would be associated with the electronic configuration 

1
1s2 , 2s2 , 2p6
2
1s2, 2s2 2p6, 3s2 3p1
3
1s2, 2s2, 2p6, 3s2, 3p
4
1s2, 2s2, 2p6, 3s2
5
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