Thermodynamics Availability and Irreversibility Available and Unavailable Energy

Availability function for a closed system is expressed as

1

ϕ = u + P₀V - T₀s

2

ϕ = du + P₀dv- T₀ds

3

ϕ = du - P₀dv - T₀ds

4

ϕ = u + P₀V + T₀s

5

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