Which one of the following pairs is not correctly matched?

1
BOD/COD = 0: Waste water is toxic
2
BOD/COD ≤ 0.2: Acclimatization of seed is necessary
3
BOD/COD ≥ 0.6: Waste water is non-biodegradable
4
BOD = COD = 0: Waste water is devoid of organic matter

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