The thermodynamic state of a closed system containing a pure fluid changes from (T1, p1) to (T2, p2), where T and p denote the temperature and pressure, respectively. Let Q denote the heat absorbed (> 0 if absorbed by the system) and W the work done (> 0 if done by the system). Neglect changes in kinetic and potential energies. Which one of the following is CORRECT?

1
Q is path-independent and W is path-dependent
2
Q is path-dependent and W is path-independent
3
(Q - W) is path-independent
4
(Q + W) is path-independent

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