The major product obtained by the reaction of PCl5 with NH3, NH4Cl and (NH4)2SO4 respectively are

1
(PNCl2)n ,P(NH2)4Cl and Cl3P = NPOCl2
2
P(NH2)4Cl, (PNCl2)n and Cl3P = NPOCl2
3
Cl3P = NPOCl2, (PNCl2)n and P(NH2)4Cl
4
[PNCl2)n only

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