At 298 K, the standard electrode potentials of Cu2+/Cu, Zn2+ /Zn, Fe2+ /Fe and Ag+ /Ag are 0.34 V, -0.76 V, -0.44 V and 0.80 V, respectively.

On the basis of standard electrode potential, predict which of the following reaction can not occur?

1
2CuSO4(aq) + 2Ag(s) → 2Cu(s) + Ag2 SO4(aq)
2
CuSO4(aq) + Zn(s) →  ZnSO4(aq) + Cu(s)
3
CuSO4(aq) + Fe(s) →  FeSO4(aq) + Cu(s)
4
FeSO4(aq) + Zn(s) →  ZnSO4(aq) + Fe(s)

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