Given:

pn0: Hole concentration in an n-type extrinsic semiconductor

ni: Intrinsic carrier concentration

Nd: Donor atom concentration

nn0: Electron concentration in an n-type extrinsic semiconductor

EFn: Fermi energy level in an n-type semiconductor

Ec: The lower end of the conduction band

Ev: The higher end of the valence band

Which of the following equations will not be valid for an n-type semiconductor under very high temperatures?

1
\({p_{n0}} = \frac{{n_i^2}}{{{N_d}}}\)
2
\({p_{n0}} = \frac{{n_i^2}}{{{n_{n0}}}}\)
3
\({E_{Fn}} = \frac{{{E_c} + {E_v}}}{2}\)
4
nn0 = Nd + pn0

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