The intrinsic Fermi level does not lie exactly at the middle of the energy band gap. 

Which of the following is a correct explanation for the following statement?

1
The effective density of state at the conduction band edge (Nc) ≠ The effective density of state at the valence band edge (Nv)
2
The effective mass of electron ≠ The effective mass of hole
3
Electron concentration and hole concentration are not equal for an intrinsic semiconductor.
4
No two electrons occupy the same energy state.

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