Starch-iodide paste/paper is used as an external indicator in one of the following titrations. Identify that.

1
Iodometric titration of copper sulphate using sodium thiosulphate as titrant
2
Iodimetric titration of ascorbic acid using iodine solution as titrant
3
Diazotization titration of sulphadiazine using sodium nitrite as titrant
4
Potassium dichromate titration using sodium thiosulphate as titrant

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