Which of the following options does not represent ground state electronic configuration of an atom?

1
1s2 2s2 2p6 3s2 3p6 3d8 4s2
2
1s2 2s2 2p6 3s2 3p6 3d9 4s2
3
1s2 2s2p6 3s2 3p6 3d10 4s1
4
1s2 2s2 2p3s2 3p6 3d5 4s1       

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