Correct order of negative inductive effect is

1
F > NO2 > Cl > Br > I > OCH3 > C6H5
2
NO2 > F > Cl > Br > I > OCH3 > C6H5
3
OCH3 > F > Cl > Br > I > C6H5  > NO2
4
NO2 > I > Br > Cl > F > C6H5  > OCH3
5
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