Chemistry Structure of Atom Atomic Structure

Which one of the following is the correct set of four quantum numbers (n, 1, m, s ) ?

1
\(\left(3,0,-1,+\frac{1}{2}\right)\)
2
\(\left(4,3,-2,-\frac{1}{2}\right)\)
3
\(\left(3,1,-2,-\frac{1}{2}\right)\)
4
\(\left(4,2,-3,+\frac{1}{2}\right)\)

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