Three buffers are made by combining a 1 M solution of acetic acid with a 1 M solution of sodium acetate in the ratios shown below.

1 M Acetic

acid

1 M sodium

acetate

Buffer 1:

10 mL

90 mL

Buffer 2:

50 mL

50 mL

Buffer 3:

90 mL

10mL

 Which of these statements is true of the resulting buffers?

1
pH of buffer 1 < pH of buffer 2 < pH of buffer 3
2
pH of buffer 1 = pH of buffer 2 = pH of buffer 3
3
pH of buffer 1 > pH of buffer 2 > pH of buffer 3
4
The problem cannot be solved without knowing the value of pka

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