According to VSEPR theory, the shapes and geometries of PCl5 and [IF5], respectively, are:

1
Trigonal bipyramidal and square pyramidal; trigonal bipyramidal and pentagonal bipyramidal
2
Octahedral and trigonal bipyramidal; square pyramidal and octahedral
3
Trigonal bipyramidal and square planar; octahedral and square pyramidal
4
Trigonal bipyramidal and Trigonal bipyramidal; square pyramidal and octahedral
5
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