1H NMR spectrum of [18] - annulene shows: 

1
Only one peak at δ 7.2 (18 H) 
2
Only one peak at δ 5.0 (18 H)
3
Two peaks at δ 9.0 (12 H) and δ -1.5 (6 H)
4
Two peaks at δ 9.0 (6 H) and δ 3.0 (12 H)
5
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