EMF of the following cell
Cu| CuSO4(aq, 1.0 mol/kg) | Hg2SO4(s)| Hg(I)| Pt
at 25° C and 1 bar is 0.36 V. The value of the mean activity coefficient (rounded off to three decimal places) of CuSO4 at 25° C 1 bar is
[Given : Standard electrode potential values at 25° C for
Cu2+ + 2e– → Cu and
Hg2SO4 + 2e– → 2Hg + SO42-:
are 0.34 V and 0.62 V, respectively.
[Consider: RT/F at 25° C = 0.0256V]
1
0.044
2
0.054
3
0.034
4
0.024
5
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