The values of CO stretching frequencies of

(1) Ni(CO)4 (2) Ni(CO)3 (PMe3) and (3) Ni(CO)2(PMe3)2

follow the trend.

1
(1) > (2) > (3)
2
(3) > (2) > (1)
3
(1) > (3) > (2)
4
(2) > (3) > (1)
5
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