The infra-red stretching frequency vco of P to S follows the order

(P) Mn (CO)6+ 

(Q) CO

(R) H3B ← CO

(S) [V (CO)6]-

1
P > R > S > Q
2
S > P > R > Q
3
Q > S > P > R
4
R > Q > P > S
5
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