Which of the following pair is INCORRECT for some transparent media with respect to air? (may consider the most approximate value)

1

Substance medium: water,

Refractive index: 1.33,

Critical angle: 48.75.

2

Substance medium: crown glass,

Refractive index: 1.12,

Critical angle: 29.14.

3

Substance medium: dense flint glass,

Refractive index: 1.62,

Critical angle: 37.31.

4

Substance medium: diamond,

Refractive index: 2.42,

Critical angle: 24.41.

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