The reaction A → P consists of the following three elementary steps with their respective activation energies

A → I (fast), Ea,1

I → A (fast), Ea,2

I → P (slow), Ea,3

Activation energy of the overall reaction is

1
Ea,1 + Ea,2 + Ea,3
2
Ea,1 + Ea,2 - Ea,3
3
Ea,2
4
Ea,1 - Ea,2 + Ea,3

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