General Science Chemistry Hydrocarbons

Which of the following is an example of substitution reaction given by Carbon compounds?

1
R2C=CR2 + Ni Catalyst + H2 →  R2HC-CHR2
2
C2H5OH + [O] → CH3COOH
3
CH4 + 2O2 → CO2 + 2H2O
4
CH4 + Cl2 → CH3Cl + HCl

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