In the transformation of oxyhemoglobin to deoxyhemoglobin:

1
\(Fe^{2+}\) in low spin state changes to \(Fe^{2+}\) in high spin state
2
\(Fe^{2+}\) in low spin state changes to \(Fe^{3+}\) in low spin state
3
\(Fe^{2+}\) in high spin state changes to \(Fe^{2+}\) in low spin state
4
\(Fe^{2+}\) in high spin state changes to \(Fe^{2+}\) in high spin state

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