The experimental magnetic moment (3.4 BM) of a hydrated salt of Eu3+ at 300 K is significantly different from calculated value. The difference is due to (Given atomic number of Eu = 63) 

1
Population of electrons at higher J level(s) via thermal excitation 
2
Strong ligand field splitting of f-orbitals  
3
Large spin-orbit coupling constant  
4
Pairing of electrons in f-orbitals  

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