In an IR spectra of 1-octyne and 4-octyne, the IR-spectra of 4-octyne does not have C ≡ C stretch absorption peak. The reason for this observation is that _________.

1
Conjugation moves stretch to lower frequency
2
4-octyne reacts with KBr while 1-octyne does not
3
4-octyne has symmetrically substituted triple bond while 1-octyne does not
4
4-octyne is inactive in IR range whereas 1-octyne is highly active

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